Professor William Gillin
Professor of Experimental Physics
Email: firstname.lastname@example.orgTelephone: 020 7882 5798Room Number: G.O. Jones Building, Room 121
William Gillin works primarily on the electrical and optical properties of organic materials. His primary research interests are in the area or organic lanthanide complexes for producing optical gain. He is also works with Paragraf Ltd on the use of vapour phase deposited graphene as a replacement for indium tin oxide in OLED devices and has a longstanding interest in organic spintronics.
Lanthanide ions, such as erbium, are widely used in optical amplifiers and lasers due to their long intrinsic lifetime which makes population inversion possible. However, this same property means that they are very poor at absorbing light so powerful pump sources, such as lasers, are required to make optical amplifiers work. By incorporating the ion into an organic host it is possible to excite the organic directly and then transfer the energy directly to the lanthanide ion; this is called sensitization. Using this approach it may be possible to replace the high power pump laser with low cost LEDs. We have developed novel fluorinated organic molecules that allow us to produce materials where the quantum efficiency of the erbium ions is >50% and which exhibit sensitization of a factor of ~10000. Using this approach we have demonstrated population inversion for the erbium ions in an organic layer deposited onto a silicon substrate when optically pumped from a low power light source. This technology has been patented and is the basis for a spin-out company Chromosol Ltd which Prof Gillin launched in 2017.
Organic spintronics is the control and manipulation of electronic spin on individual organic molecules within an organic electronic device. This technology can, for example, be used to produce devices that are highly sensitive to weak magnetic fields. We have a programme that works on producing organic spinvalves and understanding spin injection and extraction in these devices and the role of interfacial layers on controlling those processes. We also work on understanding the spin interactions that occur within devices such as organic light emitting diodes and organic photovoltaic cells. Controlling these processes is vital to improving device performance as many of the quenching mechanisms are highly spin dependent.
Replacing Indium Tin Oxide (ITO) with next-generation graphene in electronic devices, C. Humphreys, O. Fenwick, W.P. Gillin, TSB, 2018-2020, £150K
Centre for Advanced Materials for Integrated Energy Systems, EPSRC, 2016-2020, £2.1M
Silicon Photonics for Future Systems Proof of Concept Award, W.P. Gillin, EPSRC, 2015-16, £49K
Overseas Travel Grant, W.P. Gillin, EPSRC, 2014-16, £71K
Organic optical Interconnects, W.P. Gillin, EPSRC IAA Proof of Concept fund, 2013-14, £50K
Next Generation Hybrid Interfaces for Spintronic Applications (HINTS), A.J. Drew and W.P. Gillin, EU, (QMUL £301K), 2011-14, €3.87M.
Controlling spin injection interfaces in organic spinvalves, W.P. Gillin, Royal Academy of Engineering Research Exchange, 2012-13, £8K.
EPSRC, Global Engagement: Growing sustainable research collaborations with China, J. Kilburn, W.P. Gillin, L. Cuthbert, X. Chen, S. Uhlig, A. Cavallaro, E. Welch, 2012-13, £500K.
EPSRC KTA, A low cost replacement for indium tin oxide for smartphone displays, W.P. Gillin, 2011-12, £90K.
Zhu J, McMorrow J, Crespo-Otero R et al. (2016). Solution-Processable Carbon Nanoelectrodes for Single-Molecule Investigations.. nameOfConference
Ye HQ, Li Z, Peng Y et al. (2014). Organo-erbium systems for optical amplification at telecommunications wavelengths. nameOfConference
Schulz L, Nuccio L, Willis M et al. (2011). Engineering spin propagation across a hybrid organic/inorganic interface using a polar layer.. nameOfConference
Gillin WP, Zhang SJ, Rolfe NJ et al. (2010). Determining the influence of excited states on current transport in organic light emitting diodes using magnetic field perturbation. nameOfConference
Song JY, Stingelin N, Drew AJ et al. (2010). Effect of excited states and applied magnetic fields on the measured hole mobility in an organic semiconductor. nameOfConference
Drew AJ, Hoppler J, Schulz L et al. (2009). Direct measurement of the electronic spin diffusion length in a fully functional organic spin valve by low-energy muon spin rotation. nameOfConference
Desai P, Shakya P, Kreouzis T et al. (2007). Magnetoresistance and efficiency measurements of Alq(3)-based OLEDs. nameOfConference